1. bookVolume 13 (2011): Issue 4 (January 2011)
Journal Details
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03 Jul 2007
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4 times per year
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English
access type Open Access

Adsorption behavior of Pb(II) onto xanthated rubber (Hevea brasiliensis) leaf powder

Journal Details
License
Format
Journal
First Published
03 Jul 2007
Publication timeframe
4 times per year
Languages
English

A plant waste, rubber (Hevea brasiliensis) leaf powder was modified with carbon disulfide (xanthation) for the purpose of introducing sulfur groups, and the adsorbent performance in removing Pb(II) ion was evaluated. Pb(II) adsorption was confirmed by spectroscopic analysis, which involved Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX). The amount of Pb(II) adsorbed increased with increasing pH, contact time and concentration but slightly decreased with increasing ionic strength. Adsorption equilibrium was achieved in less than 60 min and followed the pseudo-second order model. The isotherm data indicated that Pb(II) adsorption on xanthated rubber leaf (XRL) fitted well with Langmuir isotherm model. The maximum adsorption capacity computed from the Langmuir isotherm model was 166.7 mg/g. Pb(II) adsorption occurred via ion-exchange and complexation mechanisms.

Keywords

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